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Purnell was born in London, U.K. She recently received the Madame Figaro Rising Star Award at the 2024 Canneseries Festival on behalf of her exciting and versatile career to date. She can be seen starring as 'Lucy MacLean' in Fallout, Prime Video's post-apocalyptic series and the platform's highest-rated show. Upcoming, she will executive-produce and star in the Sky drama series Sweetpea. Purnell's film roles include Tim Burton's Miss Peregrine's Home For Peculiar Children, Never Let Me Go, Army of the Dead, and Churchill, among others. Her other television credits include Sweetbitter, Showtime's Yellowjackets, Belgravia, and a voice role as 'Jinx' in Arcane, a Netflix animated series.